Reductive nitrosation of molybdenum and tungsten halides II. One-stage synthesis of phosphine oxide substituted mononitrosyltrichloro-, and dinitrosyldichloro-molybdenum derivatives |
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| Authors: | L. Bencze, J. Koh n, B. Mohai,L. Mark |
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| Affiliation: | Department of Organic Chemistry, Veszprém University of Chemical Engineering, 8200 Veszprém Hungary |
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| Abstract: | The reductive nitrosation of MoCl5 with NO in the presence of PPh3 in CH2Cl2 solution gives Mo(NO)Cl3 (OPPh3)2 as an intermediate and Mo(NO)2 Cl2(OPPh3)2 as a final product. In benzene solution the final product of the reaction is Mo(NO)2Cl2(OPPh3)2·2C6H6. |
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