Phase separation properties of fluorocarbons,hydrocarbons and their copolymers |
| |
| Institution: | 1. Laboratory of Green Chemistry, Lappeenranta University of Technology, Sammonkatu 12, FI-50130 Mikkeli, Finland;2. Department of Chemistry, Laboratories of Inorganic and Analytical Chemistry, PO Box 35, University of Jyväskylä, FI-40014 Jyväskylä, Finland;3. Water & Environmental Technology (WET) Center, Department of Civil and Environmental Engineering, Temple University, Philadelphia, PA 19122, USA;4. Department of Chemistry, Laboratory of Organic Chemistry, PO Box 35, University of Jyväskylä, FI-40014 Jyväskylä, Finland;1. Dermatology Department, Hospices Civils de Lyon, Pierre-Bénite, France;2. Dermatology Department, Université de Lyon, Lyon, France;3. Internal Medicine Department, Université de Lyon, Lyon, France;4. ImmuCare (Immunology Cancer Research), Institut de Cancérologie des Hospices Civils de Lyon, Lyon, France;5. Cancer Research Center of Lyon, INSERM 1052, Villeurbanne, France;6. Internal medicine department, Hospices Civils de Lyon, Pierre-Bénite, France;1. Wyatt Technology Corporation, Santa Barbara, California 93117;2. Process Development, Amgen, Thousand Oaks, California 91320 |
| |
| Abstract: | In spite of their apparently similar structures, fluorocarbons (FC) and hydrocarbons (HC) possess very different properties, and their mixtures produce experimental evidences for the formation of microdomains in the solid and in the liquid state as well.Some theoretical treatments have been proposed to explain the surprising and highly non-ideal phase separation behavior of fluorocarbons/hydrocarbons mixtures, but none of them can exhaustively offer a general and realistic framework in agreement with the experimental results. The addition of semifluorinated copolymers to FC/HC mixtures enhances their mutual solubility, and leads to the formation of supramolecular structures in the liquid state. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
