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Bismuth(III) dimethyldithioarsinate,Bi(S2AsMe2)3: A new dimer formed through Bi … S secondary bonding |
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| Authors: | Raymundo Cea-Olivares Klaus H. Ebert Luminita Silaghi-Dumitrescu Ionel Haiduc |
| Abstract: | The crystal and molecular structures of bismuth(III) dimethyldithioarsinate, Bi(S2AsMe2)2, were investigated by X-ray diffraction. The compound is a centrosymmetric dimer in which pentagonal-bipyramidal monomeric units are associated through secondary Bi–S interactions. The structure is compared with that of the analogous dithiophosphinate, Bi(S2PMe2)2. © 1997 John Wiley & Sons, Inc. |
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