Redox-active polyiron complexes with tetra(ethynylphenyl)ethene and [2,2]paracyclophane spacers containing ethynylphenyl units: extension to higher dimensional molecular wire |
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Authors: | Tanaka Yuya Ozawa Takehiro Inagaki Akiko Akita Munetaka |
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Institution: | Chemical Resources Laboratory, Tokyo Institute of Technology, R1-27, 4259 Nagatsuta, Midori-ku, Yokohama, 226-8503, Japan. |
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Abstract: | Redox active polyiron complexes with higher dimensional spacers, the tetrairon complex with the two-dimensional tetra(ethynylphenyl)ethene spacer, (C=C)p-C(6)H(4)-C triple bond C-FeCp*(dppe)](4), and the diiron complex with the three-dimensional spacer (pseudo-m-2,2]paracyclophane)C triple bond C-FeCp*(dppe)](2), are prepared, and their performance as molecular wires is evaluated on the basis of their comproportionation constants for the mixed valence state. |
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