Oxime palladacycles revisited: stone-stable complexes nonetheless very active catalysts |
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Authors: | Alacid Emilio Alonso Diego A Botella Luis Nájera Carmen Pacheco Maria Carmen |
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Institution: | Departamento de Química Orgánica and Instituto de Síntesis Orgánica, Facultad de Ciencias, Universidad de Alicante, Apartado 99, E-03080 Alicante, Spain. |
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Abstract: | Our review critically presents the main achievements, advantages, and limitations of oxime palladacycles as high-turnover catalysts for Heck, as well as homo- and cross-coupling reactions such as Suzuki-Miyaura, Stille, Ullmann-type, Cassar-Heck-Sonogashira, sila-Sonogashira, Glaser-type, Hiyama, and alkoxycarbonylation reactions. New developments in this area are reviewed from a mechanistic and synthetic point of view. The role of oxime palladacycles as a source of highly active zero-valent palladium species is also discussed. |
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Keywords: | palladacycle oxime nanoparticles catalysis cross coupling |
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