Atom Transfer Radical Polymerization of Methyl Methacrylate with α,α-Dichlorotoluene or α,α,α-Trichlorotoluene as Initiator 期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Atom Transfer Radical Polymerization of Methyl Methacrylate with α,α-Dichlorotoluene or α,α,α-Trichlorotoluene as Initiator

作者姓名：	Zhi Feng FU Yan SHI Ming Zhi HUANG Shu Ke JIAO(Department of Polymer Science. Beijing University of Chemical Technology. Beijing 100029)

摘要：	lnAtomTransferRadicalPolymerization(ATRP),whichisanew"living"/contr0lledradicalp0lymerizati0ntechniquedevel0pedindependentlybyMatyjaszewskieIallandSawam0t0eIaP,anyalkyIhalidewithactivatedsubstituents0na-carbonsuchasaryl,carb0nyl0rallylcanbeusedasinitiatoe.Benzy1haIideandpolymerswithbenzylhalideendgr0upwerereportedtobeefficientinitiator0rmacroinitiatorfortheATRPofstyrene".H0wever,whenbenzylhalidewasusedt0initiateMMAp0Iymerization,itwasfoundthattheinitiationefficiencywasveryIowinourlabo…
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