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Design and Synthesis of Cyclodextrin-Based Rotaxanes and Polyrotaxanes
Authors:Naotoshi Nakashima  Atsushi Kawabuchi  Hiroto Murakami
Abstract:Rotaxanes are compounds in which a ring is threaded by a chain having bulky terminal cap groups. In this article, we review the design, synthesis and characterization of rotaxanes and polyrotaxanes of cyclodextrins threaded by an alkyl chain or a poly(ethylene glycol) as well as the synthesis of a light-driven molecular shuttle based on a cyclodextrin-rotaxane.
Keywords:rotaxane  polyrotaxane  cyclodextrin  molecular recognition  light-driven molecular shuttle  lipid  lipid bilayer  supramolecule  nanotube
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