A new organic-inorganic hybrid based on the crescent-shaped polyoxoanion [H6SiNb18O54]8- and copper-organic cations |
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| Authors: | Huang Peng Qin Chao Wang Xin-Long Sun Chun-Yi Xing Yan Wang Hai-Ning Shao Kui-Zhan Su Zhong-Min |
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| Institution: | Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024 Jilin, People's Republic of China. |
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| Abstract: | A new organic-inorganic hybrid, Cu(en)(2)](3){Cu(en)(2)]H(6)SiNb(18)O(54)]}·22H(2)O (1, en = ethylenediamine) containing the crescent-shaped polyoxoanion H(6)SiNb(18)O(54)](8-) and copper-organic cations has been successfully synthesized, and elemental analyses, IR spectra, thermogravimetric analyses and single-crystal X-ray diffraction were investigated. |
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