The cyclic fixation and reduction of molecular nitrogen with [WH4(Ph2PCH2CH2PPh2)2] in γ-irradiated solutions |
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| Authors: | J. O. Dzigielewski J. G. Maecki |
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| Affiliation: | J. O. Dzi!["Image"]("http://www.sciencedirect.com/cache/MiamiImageURL/B6TH8-42Y106B-2B-1/0?wchp=dGLbVtb-zSkWb" "\"Image\"") gielewski,J. G. Ma!["Image"]("http://www.sciencedirect.com/cache/MiamiImageURL/B6TH8-42Y106B-2B-2/0?wchp=dGLbVtb-zSkWb" "\"Image\"") ecki |
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| Abstract: | Yields of NH3 and N2H4 in radiation-catalytic reduction of N2 by means of a hydride complex of WIV with dppe in thf solution and in mixtures of thf with other solvents have been estimated. A mechanism proposed earlier of reduction of coordinated N2 has been confirmed and the role of solvent in reduction of N2 to NH3 and amines has been explained. |
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