| Synthesis and Crystal Structure of Ag2（admtrz）2（CF3CO2）2（admtrz=4—amino—3,5—dimethyl—1,2,4—triazole） |
| |
| 引用本文： | 刘家成,郭国聪,马宏伟,杨春,周国伟,郑发鲲,林善伙,王明盛,黄锦顺. Synthesis and Crystal Structure of Ag2（admtrz）2（CF3CO2）2（admtrz=4—amino—3,5—dimethyl—1,2,4—triazole）[J]. 结构化学, 2002, 21(4): 371-373 |
| |
| 作者姓名： | 刘家成 郭国聪 马宏伟 杨春 周国伟 郑发鲲 林善伙 王明盛 黄锦顺 |
| |
| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Science |
| |
| 基金项目： | This project was financially supported by the Chinese Postdoctoral Science Foundation the National Natural Science Foundation of China and the Natural Science Foundation of Fujian Province and CAS |
| |
| 摘 要： | 1 INTRODUCTION Transition metal complexes bridged by 1, 2, 4-triazole group can produce interesting structures and specific properties[1]. Many attempts have been made to synthesize a variety of complexes with paramagnetic centers by using such ligands, and their structures and magnetic properties have been characterized[2]. However, the polynuclear Ag(I) complexes bridged by 1, 2, 4-triazole have been poorly studied[3]. Recently, we have prepared a series of silver(I) triazole complex…
|
| 关 键 词： | 银配合物 4－氨基－3,5－二甲基－1,2,4－三吡咯 合成 晶体结构 |
Synthesis and Crystal Structure of Ag2(admtrz)2(CF3CO2)2(admtrz = 4-amino-3, 5-dimethyl-1, 2, 4-triazole) |
| |
| LIU Jia-Cheng GUO Guo-Cong MA Hong-Wei YANG Chun ZHOU Guo-Wei ZHENG Fa-Kun LIN Shan-Huo WANG Ming-Sheng HUANG Jin-Shun. Synthesis and Crystal Structure of Ag2(admtrz)2(CF3CO2)2(admtrz = 4-amino-3, 5-dimethyl-1, 2, 4-triazole)[J]. Chinese Journal of Structural Chemistry, 2002, 21(4): 371-373 |
| |
| Authors: | LIU Jia-Cheng GUO Guo-Cong MA Hong-Wei YANG Chun ZHOU Guo-Wei ZHENG Fa-Kun LIN Shan-Huo WANG Ming-Sheng HUANG Jin-Shun |
| |
| Affiliation: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China |
| |
| Abstract: | The title compound (Ag2F6O4N8C12H16, Mr = 666.07) was synthesized and its crystal structure was determined by single-crystal X-ray diffraction method. It crystallizes in orthorhombic, space group Fddd with cell parameters: a = 12.2718(1), b = 23.3229(1), c = 29.1918(1) (A。）, V = 8355.10(8) (A。）3, Z = 16, Dc = 2.118 g/cm3, F(000) = 5184 and ( = 1.966 mm-1. The structure was solved by direct methods and refined by full-matrix least-squares methods. The final R = 0.0624 and Rw = 0.1699 for 1584 observed reflections with I ≥ 2.0((I). The molecular structure consists of two trigonal silver atoms bridged by double triazole ligands. The distance between the two silver atoms Ag(1)…Ag(1A) is 3.475(2) (A。）. |
| |
| Keywords: | synthesis silver 4-amino-3 5-dimethyl-1 2 4-triazole crystal structure |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
