| Synthesis and Characterization of syn-[(η~5-C_5Me_5)_2W_2(S)_2(μ-S)_2].0.5anti-[(η~5-C_5Me_5)_2W_2(S)_2(μ-S)_2] |
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| 引用本文： | 纪顺俊,虞虹,郎建平.Synthesis and Characterization of syn-[(η~5-C_5Me_5)_2W_2(S)_2(μ-S)_2].0.5anti-[(η~5-C_5Me_5)_2W_2(S)_2(μ-S)_2][J].结构化学,2002,21(3). |
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| 作者姓名： | 纪顺俊 虞虹 郎建平 |
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| 作者单位： | Department of Chemistry and Chemical Engineering，Suzhou University，Suzhou 215006，China |
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| 基金项目： | Suzhou University (XQ109020 and Q4109927) |
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| 摘 要： | 1 INTRODUCTION The complexes of syn- or anti-(5-C5Me5)2- W2(S)2(-S)2] could be prepared in several ways1~5]. For example, a mixture consisting of Et3NH](5-C5Me5)WS3] and anti-(5-C5Me5)2- W2(S)2(-S)2] was generated from the reactions of (5-C5Me5)WCl4] with H2S in the presence of NEt32]. The reactions of (5-C5Me5)W(NO)I2] with H2S led a mixture of (5-C5Me5)W(S)(S2)I] and anti-(5-C5Me5)2W2(S)2(-S)2]3]. (5-C5Me5)W- (StBu)3] was degraded in THF at room temperat…
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