| Crystal Structure of Indenyl—3—indenyl |
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| 引用本文： | 罗梅,马怀柱,苏庆德. Crystal Structure of Indenyl—3—indenyl[J]. 结构化学, 2002, 21(4): 389-391 |
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| 作者姓名： | 罗梅 马怀柱 苏庆德 |
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| 作者单位： | LUO Meia MA Huai-Zhub SU Qing-De(Department of Chemistry，University of Science and Technology of China，Hefei，Anhui 230026，China) b (Institute of Organic Chemistry，Anhui Normal University，Wuhu，Anhui 241000，China) |
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| 摘 要： | 1 INTRODUCTION Indene is an intermediate used for the synthesis of organometallic complexes involving silylene-bridged indenyl[1～5]. In the process of synthesizing (CH3)(C6H5)Si(Ind)2[6], a new compound as a by-product which is a dimer of indene was obtained, and only one similar crystal was found in CCDC[7]. Up to now, there are no crystal structure reports on this kind of structure. The present paper will describe the crystal structure of the title compound. 2 EXPERIMEN…
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| 关 键 词： | 茚 晶体结构 X射线衍射 二聚物 |
Crystal Structure of Indenyl-3-indenyl |
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| LUO Meia MA Huai-Zhub SU Qing-De. Crystal Structure of Indenyl-3-indenyl[J]. Chinese Journal of Structural Chemistry, 2002, 21(4): 389-391 |
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| Authors: | LUO Meia MA Huai-Zhub SU Qing-De |
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| Affiliation: | 1. Department of Chemistry, University of Science and Technology of China,Hefei, Anhui 230026, China
2. Institute of Organic Chemistry, Anhui Normal University, Wuhu, Anhui 241000, China |
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| Abstract: | The crystal structure of the title compound (C18H16, Mr = 232.31) has been determined by single-crystal X-ray diffraction. The crystal is of monoclinic, space group P21/n with a = 6.3449(9), b = 6.6297(9), c = 15.727(2) ? ?= 94.338(3) , ?= 0.71073 ? ?= 0.066 mm-1, V = 659.66(16) 3, Z = 2, Dc = 1.170 g/cm3 and F(000) = 248. The structure was refined to R = 0.0560 and wR = 0.1426 for 771 observed reflections with I > 2(I). X-ray diffraction analysis reveals that the title compound is a dimer of indene. |
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| Keywords: | crystal structure dimer indene |
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