Synthesis and Crystal Structure ofa Seven—coordinate Cadmium(Ⅱ)Complex |
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引用本文: | 王瑞虎,江茂椿,陈久桐,翁家宝,曹荣,赵颖隽. Synthesis and Crystal Structure ofa Seven—coordinate Cadmium(Ⅱ)Complex[J]. 结构化学, 2002, 21(3): 268-272 |
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作者姓名: | 王瑞虎 江茂椿 陈久桐 翁家宝 曹荣 赵颖隽 |
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作者单位: | State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China |
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基金项目: | This work was financially supported by the National Natural Science Foundation of China,the Key Project of Chinese Academy of Sciences |
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摘 要: | 1 INTRODUCTION In the last decade, there has been great interest in the crystal engineering of supramolecular architectures organized by coordinate covalent bonds, hydrogen bonds and their combination owing to their fascinating structural diversity and potential applications as functional materials[1~3]. The self-assembly of coordinate polymers and supramolecules is highly influenced by factors such as ligands, metal ions, the counter ions, solvent, template, reaction temperature, pH va…
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关 键 词: | 镉配合物 合成 晶体结构 氢键 X射线衍射 |
Synthesis and Crystal Structure of a Seven-coordinate Cadmium(Ⅱ) Complex |
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Abstract: | The reaction of 4-hydroxybenzoic acid (H2L),4, 4-diaminodiphenylmethane (DADPM) and Cd(NO3)2?H2O in methane/water gave rise to a seven-coordinate Cd(Ⅱ) complex [Cd2(HL)4(H2O)6]?H2O which has been characterized by single-crystal X-ray diffraction. The complex crystallizes in the orthorhombic system, space group Pna21 with unit cell parameters: a = 10.3352(3), b = 12.0481(3), c = 28.2016(1) ? V = 3511.65(13) 3, Z = 4, C28H36Cd2O20, Mr = 917.37, Dc = 1.735 g/cm3, F(000) = 1840, (MoK? = 1.29mm-1. The final R and wR are 0.0536 and 0.1086 for 4898 observed reflections with I ≥ 4(I). The Cd(Ⅱ) is seven-coordinated in a distorted pentagonal bipyramidal geometry. The inter-molecular hydrogen bonds lead to the formation of a two-dimensional layer structure. |
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Keywords: | seven-coordinate complex hydrogen bonding crystal structure |
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