Intermolecular oxygen atom?π interaction in the crystal packing of chiral amino alcohol bearing a pentafluorophenyl group |
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| Authors: | Toshinobu Korenaga |
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| Institution: | Department of Applied Chemistry, Faculty of Engineering, Okayama University, Tsushima-naka, Okayama 700-8530, Japan |
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| Abstract: | Presence of an unique atom-to-face alcoholic oxygen atom?π interaction between a pentafluorophenyl group and alcoholic oxygen (O?π) has been demonstrated by X-ray analysis of the novel chiral amino alcohol instead of the well-known interaction between usual aromatic ring and alcoholic hydrogen atom (OH?π). |
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| Keywords: | Aromatic interaction Attractive interaction Chiral ligand Amino alcohol Asymmetric synthesis |
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