Lewis acids catalyzed ring-opening reactions of methylenecyclopropanes and epoxides in supercritical carbon dioxide or modified supercritical carbon dioxide with perfluorocarbon |
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| Authors: | Min Shi Yu Chen |
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| Affiliation: | a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 354 Fenglin Lu, Shanghai 200032, China
b Department of Chemistry, East China Normal University, 3663 Zhong Shan Bei Lu, Shanghai 200062, China |
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| Abstract: | The reactions of methylenecyclopropanes (MCPs) and epoxides with alcohols and aromatic amines can be carried out in supercritical carbon dioxide (scCO2) or modified scCO2 with perfluorocarbon which offer a way to synthesize various alcohols, amino-alcohols, homoallylic ethers, and amines under an environmentally benign condition. |
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| Keywords: | Epoxides Methylenecyclopropanes (MCPs) Supercritical carbon dioxide Lewis acid Perfluorocarbon |
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