Kinetic relationships of hexachlorocyclotriphosphazatriene hydrolysis in aqueous acetonitrile in the presence of triethylamine |
| |
| Authors: | V. V. Vapirov D. O. Zaitsev |
| |
| Affiliation: | (1) Petrozavodsk State University, pr. Lenina 33, Petrozavodsk, Karelia, 185910, Russia |
| |
| Abstract: | The kinetic and thermodynamic relationships of hexachlorocyclophosphazatriene hydrolysis in aqueous acetonitrile in the presence of triethylamine were determined. The hydrolysis mechanism involving base catalysis with triethylamine is described. The halogen substitution in hexachlorocyclotriphosphazatriene occurs by the mechanism of bimolecular nucleophilic substitution. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
