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Synthesis and spectral studies of the biologically active complexes of tantalum(V) with N-alkylphenothiazines
Authors:Keshavan  Boregowda  Ramalingaiah  Hulivana
Affiliation:(1) Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore, 570 006, India
Abstract:Dioxo-bridged binuclear tantalum(V) complexes with six N-alkylphenothiazines (NAP) of general formula [TaO(L)(C2O4)]2C2O4, (L=NAP) have been prepared and characterized on the basis of elemental analysis, conductometric, magnetic and thermogravimetric data. The spectra of the complexes indicate that both the phenothiazine ligands and oxalate groups are coordinated to tantalum in a bidentate fashion, suggesting a coordination number of six around metal. The fungitoxicity of the isolated complexes against several fungi has been investigated.
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