Selective oxidation of alcohols to aldehydes by hydrogen peroxide using hexamolybdochromate(III) as catalyst |
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Authors: | S P Mardur G S Gokavi |
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Institution: | 1. Kinetics and Catalysis Laboratory, Department of Chemistry, Shivaji University, Kolhapur, 416004, Maharashtra State, India
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Abstract: | Anderson type hexamolybdochromate(III) was utilized as a catalyst for facile conversion of various aliphatic, benzylic and heterocyclic alcohols to corresponding aldehydes and ketones in good yields. The reaction was carried out in 50% aq. acetonitrile using hydrogen peroxide as the oxidant at 50 °C. The reaction was found to involve oxidation of the catalyst to its active Cr(V) intermediate by hydrogen peroxide. |
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