Alkyl metal asymmetric reduction. 11. The reaction of α,β-unsaturated ketones with β-branched trialkylaluminium compounds. |
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| Authors: | Giampaolo Giacomelli Anna Maria Caporusso Luciano Lardicci |
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| Affiliation: | Centro di Studio del C.N.R. per le Macromolecole Stereordinate ed Otticamente Attive - Istituto di Chimica Organica dell''Università, 56100 Pisa, Italy |
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| Abstract: | The reduction of a series of α,β-unsaturated ketones has been studied under various experimental conditions, by using β-branched trialkylalanes. Asymmetric induction phenomena are observed when optically active trialkylalanes are used. |
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