Scope of the palladium-catalyzed coupling reaction of organometallics with allylic electrophiles. Effect of the leaving group |
| |
| Authors: | Ei-ichi Negishi Sugata Chatterjee Hajime Matsushita |
| |
| Affiliation: | Department of Chemistry, Purdue University, W. Lafayette, Indiana 47907 U.S.A. |
| |
| Abstract: | Various allyl alcohol derivatives containing OAlR2, OPO(OR)2, and OSiR3 groups, in addition to allylic halides and acetates, participate in the Pd-catalyzed coupling reaction with alkenyl- and arylmetals, such as those containing Al, Zn and Zr.to give the corresponding cross-coupled products, the order of their reactivity being: halogen, OAc > OAlR2 > OPO(OR)2 > OSiR3. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
