Coupures alcalines d'ethers bi-tertiaires et d'alcools |
| |
| Authors: | Guido W Perold Guy Ourisson |
| |
| Institution: | 1. Laboratoire de Chimie Organique des Substances Naturelles associé au CNRS, Institut de Chimie, Université Louis Pasteur 1, rue Blaise Pascal, 67006 Strasbourg, France |
| |
| Abstract: | Heating αα′-tetrasubstituted ethers with sodium amide at 225–300° leads to smooth cleavage of one of the α-substituents, which is reduced in the process; the Intermediacy of an alkoxide ion is postulated, and a high yield cleavage of a tertiary alkoxide is indeed observed. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
