Aluminum oxide catalyzed isomerization of acylated cycloalkenes |
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| Authors: | T Hudlicky T Srnak |
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| Institution: | Department of Chemistry Illinois Institute of Technology Chicago, Illinois 60616 U.S.A. |
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| Abstract: | A homologous series of cyclic olefins and their corresponding 1-methyl derivatives were acylated using acetic anhydride/zinc chloride system. The resulting mixtures were, after appropriate analysis, isomerized quantitatively to the conjugated enones by adsorption on neutral alumina. A detailed, general experimental procedure is given. |
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