Stereochemical studies, 47, saturated heterocycles, 25 a simple stereospecific synthesis of oxazasteroids |
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Authors: | Gábor Bernáth Perenc Fülöp Gyula Argay Alajos Kálmán Pál Sohár |
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Affiliation: | 1. Institute of Pharmaceutical Chemistry, University Medical School, H-6720 Szeged, E?vös u. 6 U.K.;2. Central Research Institute of Chemistry, Hungarian Academy of Sciences, H-1525 Budapest, P,O.B. 17 Hungary;3. EGYT Pharmacochemical Works, H-1475 Budapest, P.O.B. 100, Hungary |
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Abstract: | 8-Aza-12-oxasteroids have been synthesized in a simple three-step process. As a consequence of two stareocontrolled reactions, the product is a stereospecifically homogeneous isomer with all- ring junctions; its structure has been determined by 1H and 13C NMR spectroscopy and X-ray diffraction. |
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