Kinetics and mechanism of the hydrolysis of esters of hydroxymethylphosphonic and hydroxymethylethylphosphinic acids |
| |
Authors: | V E Bel'skii A M Zotova L A Kudryavtseva B E Ivanov |
| |
Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Division, Academy of Sciences of the USSR, USSR |
| |
Abstract: | Conclusions The reactivity of ethyl esters of phosphonic and phosphinic acids containing a hydroxymethyl group at the phosphorus atom in their reaction with hydroxide anion is usually high as a consequence of intramolecular catalysis of the cleavage of the ester bond involving the ionized OH group. The spontaneous hydrolysis of these esters proceeds according to a mechanism analogous to that for other alkyl esters of tetracoordinated phosphorus acids.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2139–2140, September, 1985. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|