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Probability theory and polymer physics
Authors:Kalvis M. Jansons  L. C. G. Rogers
Affiliation:(1) Department of Mathematics, University College London, Gaver street, WCIE 6BT London, Great Britain;(2) School of Mathematical Sciences, Queen Mary and Westfield College, Mile End Road, E1 4NS London, Great Britain
Abstract:This study applies the theory of stochastic processes to the equilibrium statistical physics of polymers in solution. The topics treated include random copolymers and randomly branching polymers, with self-consistent mean field effects. A new and more natural way of dealing with Boltzmann weighting is discussed, which makes it possible from the beginning of a calculation to consider only the ldquophysicalrdquo polymer conformations. We also show that in general the random copolymer problem can be reduced to the ordinary polymer problem, and treat the self-consistent field problem for a general branching polymer.
Keywords:Probability  Brownian motion  Boltzmann weighting  branching polymers  copolymers  potential  self-contrast mean-field correction  Markov process  h-transform  conditioning  infinitesimal generator  transition semigroup  resolvent  exponential distribution
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