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Crystal Structure of L—arginine Fluoroborate
引用本文:王宏根,郑吉民,等. Crystal Structure of L—arginine Fluoroborate[J]. 结构化学, 1994, 13(2): 159-161
作者姓名:王宏根  郑吉民  
作者单位:Wang Ru-Ji;Wang Hong-Gen (Central Laboratory,Nankai University,Tianjin,300071)Zheng Ji-Min;Che Yun-Xia(Department of Chemistry,Nankai University,Tianjin,300071)
摘    要:CrystalStructureofL-arginineFluoroborateWangRu-Ji;WangHong-Gen(CentralLaboratory,NankaiUniversity,Tianjin,300071)ZhengJi-Min;...

关 键 词:晶体结构  L-米青氨酸氟硼酸  配合物  2-氨基-5-胍基戊酸

Crystal Structure of L-arginine Fluoroborate
Wang Ru-Ji,Wang Hong-Gen. Crystal Structure of L-arginine Fluoroborate[J]. Chinese Journal of Structural Chemistry, 1994, 13(2): 159-161
Authors:Wang Ru-Ji  Wang Hong-Gen
Affiliation:[1]CentralLaboratory,NankaiUniversity,Tianjin,300071 [1],NankaiUniversity,Tianjin,300071
Abstract:The title compound C_6H(15)N_4O_2·BF_4, Mr=262.03,crystallized in orthorhombic belonging to space group P2_12_12_1,a=5.050(2),b=13.619(6),c=16.470(3)A.V=1133(1)A;Z=4 ;Dc=1. 536 gcm-3,F(000)=544,μ=1.462 cm ̄(-1)(MoKα).The final R=0.082 and Rw=0. 081 for 673 independent observed reflections with I≥3σ(Ⅰ).The title compound is a 1:1 ionic complex of L-arginine and fluoroborate,and both the amino and guanidyl groups of L-arginine are protonated. There are a lot of hydrogen bonds in this crystal which link the discrete L-arginine and fluoroborate to form a three-dimensional network.
Keywords:crystal structure  L-arginine fluoroborate  non-linear optical
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