| 生物表面活性剂胆汁盐胶束化及相行为 |
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| 引用本文： | 吴同浩,王仲妮. 生物表面活性剂胆汁盐胶束化及相行为[J]. 化学进展, 2011, 23(1): 80-89 |
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| 作者姓名： | 吴同浩 王仲妮 |
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| 作者单位： | 山东师范大学化学化工与材料科学学院 分子与纳米探针教育部重点实验室 济南 250014 |
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| 基金项目： | 国家自然科学基金项目(No.31071603) 资助 |
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| 摘 要： | 生物表面活性剂胆汁盐类以其在生物体内重要的生理功能及不同于传统表面活性剂独特的结构特点在众多领域引起了广泛的关注。本文对国内外关于胆汁盐类表面活性剂的胶束结构、表面吸附行为及胆汁盐在水溶液中的聚集体行为的研究成果进行了综述。同时,对胆汁盐与传统表面活性剂、双尾表面活性剂及天然脂类表面活性剂的相互作用以及聚集体的形成、胆汁盐诱导聚集体结构转变等方面的研究成果也进行了综述。
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| 关 键 词： | 胆汁盐 胶束化 相行为 表面吸附 分子间相互作用 |
| 收稿时间： | 2010-06-01 |
| 修稿时间： | 2010-09-01 |
Micellization and Phase Behavior of Biosurfactant Bile Salts |
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| Wu Tonghao Wang Zhongni. Micellization and Phase Behavior of Biosurfactant Bile Salts[J]. Progress in Chemistry, 2011, 23(1): 80-89 |
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| Authors: | Wu Tonghao Wang Zhongni |
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| Affiliation: | College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Molecular and Nano Probe, Ministry of Education, Shandong Normal University, Jinan 250014, China |
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| Abstract: | Biosurfactant bile salts have attracted wide attention in many fields due to their important physiological function and unique structural characteristics different from the conventional surfactants. In this paper, recent progress in research of bile salts have been reviewed, including the micellar structure, surface adsorption behavior and self-assembly behavior of bile salts in aqueous solution. The development of molecular interactions and the aggregations formed in the systems of bile salts/conventional surfactants, bile salts/double-tailed surfactants and bile salts/natural lipid surfactants, as well as bile salts-induced structural transition in self-assemblies have also summarized. |
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| Keywords: | bile salts micellization phase behavior surface adsorption molecular interaction |
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