| 有机硅化合物在α-D-葡二糖合成上的应用 |
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| 引用本文： | 费昌沛. 有机硅化合物在α-D-葡二糖合成上的应用[J]. 化学学报, 1990, 48(2): 180-184 |
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| 作者姓名： | 费昌沛 |
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| 作者单位： | 麦吉尔大学化学系 |
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| 摘 要： | 三苯基硅基作为葡萄糖1-C位羟基保护基, 在对硝基苯甲酰基存在下形成和脱保护基反应均易进行, 而且有产率高、在反应过程中保持1-C构型不变等特点, 并研究了三苯基硅基保护基在葡二糖上的应用。
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| 关 键 词： | 葡萄糖 硝基苯P 苯甲酸P 硅化合物 有机硅化合物 三苯基甲烷 保护基 二糖 |
Application of organosilicon compounds in the synthesis of -D-glucobiose |
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| FEI CHANGPEI. Application of organosilicon compounds in the synthesis of -D-glucobiose[J]. Acta Chimica Sinica, 1990, 48(2): 180-184 |
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| Authors: | FEI CHANGPEI |
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| Abstract: | Triphenylsilyl group can be used as protective group for 1-OH in glucopyranose. The silyl group can be formed and deprotected readily in the presence of the p-nitrobenzoate group. The configuration at 1-C was not changed during the reactions. The use of triphenylsilyl group in the synthesis of a disaccharide I was demonstrated. |
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| Keywords: | GLUCOSE NITROBENZENE P BENZENECARBOXYLIC ACID P SILICON COMPOUNDS ORGANO SILICON COMPOUNDS TRIPHENYLMETHANE PROTECTIVE GROUP DISACCHARIDE |
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