Reverse orthogonal strategy for oligosaccharide synthesis |
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| Authors: | Fujikawa Kohki Ganesh N Vijaya Tan Yih Horng Stine Keith J Demchenko Alexei V |
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| Institution: | Department of Chemistry and Biochemistry, University of Missouri-St. Louis, One University Boulevard, St. Louis, Missouri 63121, USA. |
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| Abstract: | Herein, we report the invention of a novel expeditious concept for oligosaccharide synthesis. Unlike the classic orthogonal strategy based on leaving groups, the reverse approach is based on orthogonal protecting groups, herein p-methoxybenzyl and 4-pentenoyl, which allows for efficient oligosaccharide assembly in the reverse direction. |
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