Charge-transfer properties of lateral triphenylamine-dithienophosphole diads |
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| Authors: | Chua Chris Jansen Ren Yi Baumgartner Thomas |
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| Institution: | Department of Chemistry & Centre for Advanced Solar Materials, University of Calgary, 2500 University Drive NW, Calgary, AB T2N 1N4, Canada. |
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| Abstract: | Installation of an exocyclic triphenylamine group at the phosphorus center provides access to dithienophosphole materials with lateral charge-transfer (CT) ability. The degree of CT can be significantly manipulated not only via oxidation of the P-center but also surprisingly by alkylation of the 2,6-position of the scaffold. |
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