Inside back cover: highly stereoselective metal-free oxyaminations using chiral hypervalent iodine reagents (angew. Chem. Int. Ed. 14/2012) |
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| Authors: | Farid Umar Wirth Thomas |
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| Affiliation: | School of Chemistry, Cardiff University, Park Place, Main Building, Cardiff CF10 3AT (UK) http://www.cf.ac.uk/chemy/wirth. |
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| Abstract: | About 30?% of the world's iodine production comes from the Chiba area in Japan, shown in the background of the picture (Map data (?) 2012 ZENRIN Imagery (?) 2012 TerraMetrics). Enantiomerically pure hypervalent iodine compounds are the key for metal-free, highly stereoselective oxyaminations of alkenes. In their Communication on page?3462?ff., T. Wirth and U. Farid report the use of the reaction for the facile synthesis of 2-arylprolinols. |
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| Keywords: | amino alcohols aminohydroxylation cyclization hypervalent iodine stereoselective synthesis |
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