One-pot synthesis of hybrid TiO2-polyaniline nanoparticles by self-catalyzed hydroamination and oxidative polymerization from TiO2-methacrylic acid nanoparticles |
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| Authors: | Bae Woo Jin Davis Andrew R Jung Jaewoong Jo Won Ho Carter Kenneth R Coughlin E Bryan |
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| Institution: | Department of Polymer Science and Engineering, University of Massachusetts Amherst, Conte Center for Polymer Research, 120 Governors Drive, Amherst, Massachusetts 01003, USA. |
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| Abstract: | A simple self-catalyzed hydroamination method for creating hybrid TiO(2)-polyaniline core-shell nanoparticles (NP) has been shown. Hybrid NPs with a range of possible sizes are afforded in high yield under mild reaction conditions and simultaneously show improved charge transport and electrochromic behavior compared to either polyaniline alone or physically blended with TiO(2). |
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