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Rhenium-catalyzed allylation of C-H bonds of benzoic and acrylic acids
Authors:Kuninobu Yoichiro  Ohta Kazuhiro  Takai Kazuhiko
Affiliation:Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima, Okayama 700-8530, Japan. kuninobu@cc.okayama-u.ac.jp
Abstract:We have succeeded in the allylation of aromatic and olefinic C-H bonds of benzoic and acrylic acids using a rhenium catalyst, Re(2)(CO)(10). In this reaction, isomerization of the introduced allyl group to the 1-propenyl group did not occur.
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