Rhenium-catalyzed allylation of C-H bonds of benzoic and acrylic acids |
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| Authors: | Kuninobu Yoichiro Ohta Kazuhiro Takai Kazuhiko |
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| Institution: | Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima, Okayama 700-8530, Japan. kuninobu@cc.okayama-u.ac.jp |
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| Abstract: | We have succeeded in the allylation of aromatic and olefinic C-H bonds of benzoic and acrylic acids using a rhenium catalyst, Re(2)(CO)(10). In this reaction, isomerization of the introduced allyl group to the 1-propenyl group did not occur. |
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