Interdimensional degeneracies in van der Waals clusters and quantum Monte Carlo computation of rovibrational states |
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Authors: | Nightingale M P Moodley Mervlyn |
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Affiliation: | Department of Physics, University of Rhode Island, Kingston, Rhode Island 02881, USA. nigh@phys.uri.edu |
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Abstract: | Quantum Monte Carlo estimates of the spectrum of rotationally invariant states of noble gas clusters suggest interdimensional degeneracy in N-1 and N+1 spatial dimensions. We derive this property by mapping the Schrodinger eigenvalue problem onto an eigenvalue equation in which D appears as a continuous variable. We discuss implications for quantum Monte Carlo and dimensional scaling methods. |
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