| 关于电化学极化能否改变电极内部费米能级位置的讨论 |
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| 引用本文： | 查全性. 关于电化学极化能否改变电极内部费米能级位置的讨论[J]. 物理化学学报, 1986, 2(5): 478-480. DOI: 10.3866/PKU.WHXB19860515 |
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| 作者姓名： | 查全性 |
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| 作者单位： | Department of Chemistry; Wuhan University |
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| 摘 要： | Khan等人近年一再发表关于电化学极化不能影响电极内部费米能级以及改变电极和溶液两相内部费米能级相对位置的观点。在[3]中更详细地阐述了这种观点。按照作者的意见,根据 E_F=h~2/8π~2m_■~*(3π~2n_e)~2/3 (1)(式中m_■~*为电子的有效质量,n_e是自由电子的浓度,见[3]中第309页,但原文中n_e误写作分母),由于在良电子导体中电场不能进入整体相内部,其中的剩余电荷只可能分布在距
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| 收稿时间： | 1986-03-15 |
| 修稿时间： | 1986-06-02 |
POSSIBLE EFFECT OF ELECTROCHEMICAL POLARIZATION ON THE POSITION OF FERMI-LEVEL WITHIN BULK OF ELECTRODE |
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| Cha Chuansin. POSSIBLE EFFECT OF ELECTROCHEMICAL POLARIZATION ON THE POSITION OF FERMI-LEVEL WITHIN BULK OF ELECTRODE[J]. Acta Physico-Chimica Sinica, 1986, 2(5): 478-480. DOI: 10.3866/PKU.WHXB19860515 |
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| Authors: | Cha Chuansin |
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| Affiliation: | Department of Chemistry; Wuhan University |
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| Abstract: | The view point that electrochemical polarization has no effect on the position of Fermi-level within bulk of electrode had been stated in [1—3]. Apparently, there was some confusion between the concepts of kinetic Fermi energy and the position of Fermi-level relative to electron in the vaccum. |
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