| Synthesis and Structure Characterization of a Manganese（II） Complex With Eight Coordination Geometry： [Mn（OeCMe）e（phen）2] |
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| 作者姓名： | WANG Mei MA Cheng-Bing WANG Hui-Sheng CHEN Chang-Neng LIU Qiu-Tian |
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| 作者单位： | [1]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on theStructure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China [2]Graduate School of the Chinese Academy of Sciences, Beijing 100039, China |
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| 基金项目： | This project was supported by the NNSFC （No. 20471061） and the Science ＆ Technology Innovation Foundation for the Young Scholars of Fujian Province （No. 2005J059） |
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| 摘 要： | The title compound [Mn（O2CMe）2（phen）2] （phen = 1,10-phenanthroline） 1 has been synthesized and structurally determined by single-crystal X-ray diffraction. The crystal is of orthor- hombic, space group Pbcn, with a = 12.554（4）, b = 10.168（3）, c = 17.704（5）A, V= 2259.7（12）A^3 Z = 4, C28H22MnN4O4, Mr= 533.44, Dc= 1.568 g]cm^3, F（000） = 1100, Rint = 0.0242, T= 293（2） K and p = 0.631 mm^-1. The final R = 0.0687 and wR = 0.1960 for 2046 observed reflections with I 〉 20（/）. The structure of the complex consists of one Mn（II） core coordinated by two bidentate-bound CH3COO^- groups and two η^2-phen groups forming an eight-coordinate geometrical configuration.
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| 关 键 词： | 锰配合物 结构分析 晶体结构 光合体系 八配位体 |
| 收稿时间： | 2006-11-03 |
| 修稿时间： | 2006-11-032006-12-21 |
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