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ZnO纳米管的制备及光学特性研究
引用本文:王福学,蔡小龙,闫大为,朱兆旻,肖少庆,顾晓峰.ZnO纳米管的制备及光学特性研究[J].半导体学报,2014,35(9):093004-5.
作者姓名:王福学  蔡小龙  闫大为  朱兆旻  肖少庆  顾晓峰
基金项目:省自然科学基金;其它;国家自然科学基金
摘    要:ZnO nanotubes have been fabricated through a carbon thermal reduction deposition process. Structure characterization results show that the ZnO nanotubes have a single crystalline wurtzite hexagonal structure pref- erentially oriented in the c-axis. The diameters of ZnO nanotubes are in the range of 90-280 nm and the wall thickness is about 50-100 nm. Room-temperature photoluminescence measurements of the ZnO nanotubes exhibit an intensive ultraviolet peak at 377 nm and a broad peak centered at about 517 nm. The UV emission is caused by the near band edge emission while the green emission may be attributed to both oxygen vacancy and the surface state. Raman and cathodoluminescence spectra are also discussed. Finally, a possible growth mechanism of the ZnO nanotubes is proposed.

关 键 词:纳米管  发光特性  氧化锌  合成  沉积过程  碳热还原  结构表征  六方结构

Synthesis and luminescence characteristics of ZnO nanotubes
Wang Fuxue,Cai Xiaolong,Yan Dawei,Zhu Zhaomin,Xiao Shaoqing and Gu Xiaofeng.Synthesis and luminescence characteristics of ZnO nanotubes[J].Chinese Journal of Semiconductors,2014,35(9):093004-5.
Authors:Wang Fuxue  Cai Xiaolong  Yan Dawei  Zhu Zhaomin  Xiao Shaoqing and Gu Xiaofeng
Institution:Key Laboratory of Advanced Process Control for Light Industry (Ministry of Education), Department of Electronic Engineering, Jiangnan University, Wuxi 214122, China;Key Laboratory of Advanced Process Control for Light Industry (Ministry of Education), Department of Electronic Engineering, Jiangnan University, Wuxi 214122, China;Key Laboratory of Advanced Process Control for Light Industry (Ministry of Education), Department of Electronic Engineering, Jiangnan University, Wuxi 214122, China;Key Laboratory of Advanced Process Control for Light Industry (Ministry of Education), Department of Electronic Engineering, Jiangnan University, Wuxi 214122, China;Key Laboratory of Advanced Process Control for Light Industry (Ministry of Education), Department of Electronic Engineering, Jiangnan University, Wuxi 214122, China;Key Laboratory of Advanced Process Control for Light Industry (Ministry of Education), Department of Electronic Engineering, Jiangnan University, Wuxi 214122, China
Abstract:ZnO nanotubes have been fabricated through a carbon thermal reduction deposition process. Structure characterization results show that the ZnO nanotubes have a single crystalline wurtzite hexagonal structure preferentially oriented in the c-axis. The diameters of ZnO nanotubes are in the range of 90-280 nm and the wall thickness is about 50-100 nm. Room-temperature photoluminescence measurements of the ZnO nanotubes exhibit an intensive ultraviolet peak at 377 nm and a broad peak centered at about 517 nm. The UV emission is caused by the near band edge emission while the green emission may be attributed to both oxygen vacancy and the surface state. Raman and cathodoluminescence spectra are also discussed. Finally, a possible growth mechanism of the ZnO nanotubes is proposed.
Keywords:ZnO  nanotubes  photoluminescence  cathodoluminescence  growth mechanism
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