| (甲基)丙烯酸酯的基团转移聚合 |
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| 引用本文： | 邹友思,潘容华.(甲基)丙烯酸酯的基团转移聚合[J].高分子学报,1988,0(4):301-304. |
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| 作者姓名： | 邹友思 潘容华 |
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| 作者单位： | 厦门大学化学系
(邹友思)，厦门大学化学系(潘容华) |
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| 摘 要： | <正> 基团转移聚合方法自问世以来,由于其突出的优点,受到日益广泛的重视。本文来用丙二酸二乙酯的硅烯醇醚类引发剂3-乙氧基-3-三甲基硅氧基丙烯酸乙酯 (CH_3CH_2O_2CCH=C(OCH_2CH_3)OSiMe_3)和亲核型催化剂四乙基二氯化氢氨((CH_3CH_2)_4NHF_2)进行甲基丙烯酸甲酯(MMA)、丙烯酸丁酯(BA)、丙烯酸乙酯(EA)和丙烯酸甲酯(MA)的基因转移聚合。得到了近
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| 关 键 词： | 基团转移聚合 聚甲基丙烯酸甲酯 聚丙烯酸酯 单分散 |
| 收稿时间： | 1987-07-07 |
GROUP TRANSFER POLYMERIZATION OF (METH) ACRYLATES |
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| ZOU You-si,PAN Rong-hua.GROUP TRANSFER POLYMERIZATION OF (METH) ACRYLATES[J].Acta Polymerica Sinica,1988,0(4):301-304. |
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| Authors: | ZOU You-si PAN Rong-hua |
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| Institution: | Department of Chemistry; Xiamen University; Xiamen |
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| Abstract: | This work deals with the group transfer polymerization (GTP) of methyl methacrylate and some acrylates, with ethyl 3-ethoxy-3-trimethylsiloxyacrylate (ETSA) as initiator and Et4NHF2 as catalyst. Monodisperse polymer with predetermined molecular weights can be obtained by adjusting the monomer/initiator ratio. "Auto-acceleration" can be avoided by decreasing the catalyst concentration. |
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| Keywords: | Group Transfer Polymerization Polymethyl Methacrylate Polyacrylate Monodisperse Polymer |
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