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Reactions of 2-methylindole with morpholinals of substituted salicylaldehydes |
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| Authors: | Ukhin L. Yu. Belousova L. V. Khrustalev V. N. |
| Affiliation: | (1) Institute of Physical and Organic Chemistry, Rostov State University, 194/2 prosp. Stachki, 344090 Rostov-on-Don, Russian Federation;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation |
| Abstract: | Fusion of 2-methylindole with morphinals of substituted salicylaldehydes (in a ratio of 1 : 1) afforded 3-[(2-hydroxyaryl)morpholinomethyl]-2-methylindoles as normal products of the Mannich reaction. In some cases, the reactions with an excess of 2-methylindole resulted in unusual condensation accompanied by the replacement of the OH group by the morpholino group to form bis(2-methylindol-3-yl)(2-morpholinoaryl)methanes. |
| Keywords: | 2-methylindole morpholinals of substituted salicylaldehydes 3-[(2-hydroxyaryl)morpholinomethyl]-2-methylindoles bis(2-methylindol-3-yl)(2-morpholinoaryl)methanes |
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