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Stereoselective synthesis of (Z,E)-bis(2-chloroethenyl)tellanes
Authors:M. V. Musalova  A. G. Khabibulina  V. A. Potapov  S. V. Amosova
Affiliation:1.Favorskii Irkutsk Institute of Chemistry, Siberian Branch,Russian Academy of Sciences,Irkutsk,Russia
Abstract:A procedure for the stereoselective synthesis of dichloro[(Z)-2-chloro-2-phenylethenyl][(4E)-5- chlorooct-4-en-4-yl]-λ4-tellane and [(Z)-2-chloro-2-phenylethenyl][(4E)-5-chlorooct-4-en-4-yl]tellane has been developed on the basis of anti-addition of tellurium tetrachloride–phenylacetylene monoadduct to oct-4-yne.
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