Synthesis of polyfluoralkylated 1,3,2-dioxaphospholane and 1,3,2-dioxaphosphorinane oxides |
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| Authors: | N K Gusarova S I Verkhoturova S N Arbuzova T I Kazantseva A I Albanov A M Nalibaeva G K Bishimbaeva |
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| Institution: | 1.Favorskii Irkutsk Institute of Chemistry, Siberian Branch,Russian Academy of Sciences,Irkutsk,Russia;2.Institute of Fuel, Catalysis, and Electrochemistry,Almaty,Kazakhstan |
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| Abstract: | Polyfluoroalkyl dichlorophosphates easily react with 1,2- or 1,3-alkanediols in a system pyridine–diethyl ether and afford 2-polyfluoroalkoxy-1,3,2-dioxaphospholane oxides or 2-polyfluoroalkoxy-1,3,2-dioxaphosphorinane oxides. In similar conditions the reaction of methyl dichlorophosphate with 1,2- and 1,3-alkanediols proceeds less effectively. |
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