Synthesis of bis(2-haloalkyl) selanes and selenides based on selenium dioxide and terminal alkenes |
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Authors: | M V Musalov E O Kurkutov V A Potapov A G Khabibulina A I Albanov S V Amosova |
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Institution: | 1.Favorskii Irkutsk Institute of Chemistry, Siberian Branch,Russian Academy of Sciences,Irkutsk,Russia |
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Abstract: | Selenium tetrahalides generated from selenium dioxide and hydrogen halides (HCl, HBr) reacted with hex-1-ene, hept-1-ene, and oct-1-ene at a SeO2?alkene molar ratio of 1: 2 to give mixtures of dihalobis-(2-haloalkyl)-λ4-selanes (yield 80?90%) and bis(2-haloalkyl) selenides (yield 5?12%). Halogenation of the resulting mixtures afforded 85?93% (calculated on the initial SeO2) of the corresponding dihalobis(2-haloalkyl)-λ4-selanes, and the reduction of the same mixtures with Na2S2O5 gave bis(2-haloalkyl) selenides in 80?86% yield. In the reaction with a SeO2?alkene ratio of 5: 8, pure dihalobis(2-haloalkyl)-λ4-selanes were formed in 84?93% yield. Dichlorobis(2-chloro-2-phenylethyl)-λ4-selane was obtained in 72% yield in the reaction of SeO2?HCl with styrene. |
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