Arylation of adamantanamines: IX. Copper(I)-catalyzed arylation of adamantane-containing amines |
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| Authors: | A. D. Averin S. P. Panchenko A. S. Abel O. A. Maloshitskaya G. M. Butov E. N. Savelyev B. S. Orlinson I. A. Novakov I. P. Beletskaya |
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| Affiliation: | 1.Faculty of Chemistry,Moscow State University,Moscow,Russia;2.Frumkin Institute of Physical Chemistry and Electrochemistry,Russian Academy of Sciences,Moscow,Russia;3.Volzhskii Polytechnic Institute,Branch of Volgograd State Technical University,Volzhskii, Volgograd oblast,Russia;4.Volgograd State Technical University,Volgograd,Russia |
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| Abstract: | Copper(I)-catalyzed arylation of 14 adamantane-containing amines with iodobenzene, 1-fluoro-4-iodobenzene, 1-iodo-4-(trifluoromethyl)benzene, and 1-iodo-4-methoxybenzene has been studied under the conditions optimized previously. The yields of the N-arylation products have been shown to depend in a complicated manner on the amine structure, steric environment of the amino group, and substituent nature in iodobenzene. |
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