Synthesis of [3-(trimethylsilyl)prop-2-yn-1-yl] selenides |
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| Authors: | M V Musalov M V Andreev S V Amosova L I Larina V A Potapov |
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| Institution: | 1.Favorskii Irkutsk Institute of Chemistry, Siberian Branch,Russian Academy of Sciences,Irkutsk,Russia |
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| Abstract: | Efficient and selective methods have been developed for the synthesis of previously unknown organyl 3-(trimethylsilyl)prop-2-yn-1-yl] selenides, organyl prop-2-yn-1-yl selenides, and bis3-(trimethylsilyl) prop-2-yn-1-yl] selenide by reactions of 3-bromo-1-(trimethylsilyl)prop-1-yne with the corresponding organylselenolates and sodium selenide generated from diorganyl diselenides or elemental selenium by the action of sodium tetrahydridoborate. |
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