Synthesis of ethyl ({[adamantan-1(2)-ylalkyl]-carbamothioyl}amino)acetates |
| |
| Authors: | V V Burmistrov D A Pitushkin V V Vasipov G M Butov |
| |
| Institution: | 1.Volzhskii Polytechnic Institute (Branch) at Volgograd State Technical University,Volzhskii,Russia;2.Peter the Great St. Petersburg Polytechnic University,St. Petersburg,Russia |
| |
| Abstract: | Reactions of adamantan-1(2)-amines and adamantan-1(2)-ylalkanamines with ethyl isothiocyanatoacetate afforded ethyl ({adamantan-1(2)-ylalkyl]carbamothioyl}amino)acetates in 85–95% yields. The hydrolysis of ethyl {(adamantan-2-yl)carbamothioyl]amino}acetate in alkaline medium resulted in the formation of {(adamantan-2-yl)carbamothioyl]amino}acetic acid in a virtually quantitative yield. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
