Synthesis,structure, and magnetic properties of a Yb<Superscript>III</Superscript> complex with the iminopyridine radical-anionic ligand期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Synthesis,structure, and magnetic properties of a YbIII complex with the iminopyridine radical-anionic ligand

Authors:	A.?A.?Trifonov author-information" > author-information__contact u-icon-before" > mailto:trif@iomc.ras.ru" title=" trif@iomc.ras.ru" itemprop=" email" data-track=" click" data-track-action=" Email author" data-track-label=" " >Email author,B.?G.?Shestakov,D.?M.?Lyubov,K.?A.?Lyssenko

Affiliation:	1.A. N. Nesmeyanov Institute of Organoelement Compounds,Russian Academy of Sciences,Moscow,Russian Federation;2.G. A. Razuvaev Institute of Organometallic Chemistry,Russian Academy of Sciences,Nizhny Novgorod,Russian Federation

Abstract:	The reaction of equimolar amounts of ytterbocene (C₅Me₄H)₂Yb(THF)₂ and iminopyridine 2,6-Prⁱ₂C₆H₃N=CH(C₅H₄N) accompanied by the one-electron oxidation of the ytterbium ion produced the unique lanthanide complex (C₅Me₄H)₂Yb^III[2,6-Prⁱ₂-C₆H₃NCH(C₅H₄N)]–? with the iminopyridine radical-anionic ligand. The structure of the complex in the crystalline state was established by X-ray diffraction and its magnetic properties were studied in the temperature range of 1.8—300 K.

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