Synthesis and Isomer Composition of 2-Polyfluoroalkoxy-1,3,2-dioxaphospholanes and -phosphinanes |
| |
Authors: | N?K?Gusarova S?I?Verkhoturova S?N?Arbuzova T?I?Kazantseva A?I?Albanov A?M?Nalibaeva G?K?Bishimbaeva K?A?Apartsin V?V?Kireeva Email author" target="_blank">B?A?TrofimovEmail author |
| |
Institution: | 1.Favorskii Irkutsk Institute of Chemistry, Siberian Branch,Russian Academy of Sciences,Irkutsk,Russia;2.Sokol’skii Institute of Fuel,Catalysis, and Electrochemistry,Almaty,Kazakhstan;3.Medical and Biological Research and Technology Department, Irkutsk Scientific Center, Siberian Branch,Russian Academy of Sciences,Irkutsk,Russia |
| |
Abstract: | Polyfluoroalkanols readily reacted with 2-chloro-1,3,2-dioxaphospholanes and 2-chloro-1,3,2-dioxaphosphinanes in hexane in the presence of triethylamine (–10 to 25°C, 5 h) to give 2-polyfluoroalkoxy-1,3,2- dioxaphospholanes and 2-polyfluoroalkoxy-1,3,2-dioxaphosphinanes in 48–72% yield. The products were found to exist as mixtures of cis and trans isomers with the trans isomer predominating for the phospholanes and cis isomer predominating for the phosphinanes according to the 1H, 13C, 19F, and 31P NMR data. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|