1.International Tomography Center, Siberian Branch,Russian Academy of Sciences,Novosibirsk,Russia;2.Novosibirsk State University,Novosibirsk,Russia
Abstract:
A mixed ligand complex of Ni(II) with 3-imidazoline nitroxide and iso-propanol NiL2(i-C3H7OH)2] is sensitive to atmospheric moisture. It is determined that at a high humidity, the air contacts with the mother solution of the compound in iso-propanol with the precipitated NiL2(i-C3H7OH)2] crystals leads to their spontaneous transformation into NiL2(H2O)]·i-C3H7OH crystals whose structure is described in the present paper.