<Emphasis Type="Italic">In situ</Emphasis> X-ray spectroscopic investigation of thermal decomposition of double complex salt [Pt(NH<Subscript>3</Subscript>)<Subscript>4</Subscript>][OsCl<Subscript>6</Subscript>]期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

In situ X-ray spectroscopic investigation of thermal decomposition of double complex salt [Pt(NH3)4][OsCl6]

Authors:	T.?I.?Asanova author-information" > author-information__contact u-icon-before" > mailto:nti@niic.nsc.ru" title=" nti@niic.nsc.ru" itemprop=" email" data-track=" click" data-track-action=" Email author" data-track-label=" " >Email author,I.?P.?Asanov,M.-G.?Kim,S.?V.?Korenev

Affiliation:	1.Nikolaev Institute of Inorganic Chemistry Siberian Branch,Russian Academy of Science,Novosibirsk,Russia;2.Novosibirsk National Research University,Novosibirsk,Russia;3.Beamline Research Division,Pohang University of Science and Technology,Pohang,Republic of Korea

Abstract:	In the paper results of the investigation of the thermal decomposition process of double complex salt [Pt(NH₃)₄][OsCl₆] by x-ray absorption (XAFS) and photoelectron (XPS) spectroscopies have been presented. The data obtained allows a mechanism of the thermal decomposition to be refined. An influence of size effect and nanoalloy formation on chemical shift of Pt and Os is discussed.

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